Property Comparison of Various Fluoropolymers

Property ASTM test method/test condition PTFE PFA FEP ETFE CTFE


Physical Properties

Specific gravity D792
D570/24 hrs 1/2"t
2.13~2.22 2.12~2.17 2.12~2.17 1.70~1.76 2.10~2.18
Water absorption (%)   <0.00 <0.03 <0.01 <0.1 <0.00
Mold shrinkage (cm/cm)   0.02 ~0.05 0.04 0.03~0.06 0.03~0.04 0.015~0.020
Contact angle (degree) Angle to level 110 115 115 96 84

Thermal Properties

Thermal conductivity (cal/sec/cm)

C177 6 X 10-4 6 X 10-4 5.7 X 10-4 4.7~5.3
X 10-4
Coefficient of linear thermal expansion (1/°C) D696/23~60°C 10 X 10-5 12 X 10-5
8.3~10.5
X 10-5
5~9 X 10-5 4.5 ~ 7.0 X
10-5
Melting point (°C) 327 302~310 270 260 210~212

Melt viscosity (coise)

10-11~10-13
(340-380°C)
10-4~10-5
(380°C)
4X10-4
~10-5
(380°C)
10-4~10-5
(300-330°C)
10-7
(23°C)
Maximum temp. for continuous use
(°C/°F)
260/500 260/500 200/392 150/302 120/248

Mechanical Properties
Tensile strength
(kgf/cm2)
D638/23°C
140~350 280~315 190~220 410~470 320~420
Elongation (%) D638/23°C 200~400 280~300 250~330 420~440 80~250
Compression strength (kgf/cm2) D695/1% deformation, 25°C 50~60 50~60 50~60 109 90~120
Tensile modulus
(kgf/cm2)
D638/23°C 4,000 3,500 5,000~8,000 10,500~21,000
Hexural Modulus
(kgf/cm2)
D790/23°C 5,000~6,000 6,600~7,000 5,500~6,500 9,000~14,000 13,000~18,000
Impact strength
(ft-lb/ln)
D256/23°C lzod 3.0 No breakdown No breakdown 2.5~2.7
Hardness (Shore) Durometer D50~D65 D60 D55 D75 D90
Deformation under load (%) D621/100°C
70 kfg/cm2,
24 hrs
D621/25°C
140 kgf/cm2,
24 hrs

5.0

7.0

2.4

2.7

5.0

3.0

5.4

2.3

2.6

0.2

Static friction coefficient Coated steel surface 0.20 0.50 0.50 0.60 0.80

Electrical Properties
Dielectric constant

D150/103Hz
D150/108Hz

2.1
2.1
2.1
2.1
2.1
2.1
2.6
2.6
2.3~2.7
2.3~2.5
Dielectric dissipation factor D150/103HZ
D150/108HZ
<1 X 10-5
2 X 10-5
1 X 10-5
3 X 10-5
6 X 10-5
5 X 10-5
8 X 10-4
5 X 10-3
(2.3~2.7)
X10-2
1 X 10-2
Dielectric breakdown
strength (V/ml)
D149/Short time, 1/8 in 480 500 500~600 400 500
Volume resistivity (ohm-cm) D257 >10-18 >10-18 >10-18 >10-18 >10-18
Chemical resistance Weatherability Combustibility (%)

D2863/Oxygen
concentration index
Excellent

Excellent
>95
Excellent

Excellent
>95
Excellent

Excellent
>95
Excellent

Excellent
>31
Excellent

Excellent
>95


Typical Filler Properties

Filler
Physical Form
Amount (% Weight)
Effect of Filler

Glass Fibers
Milled Fibers
up to 40%
(also in combination with graphite, MoS2 and carbon)
  • increased compressive strength
  • increased rigidity
  • increased wear resistance
  • reduced cold flow
  • resistant to organic solvent

Carbon

Carbon Fibers

Powder

Milled Fibers

up to 25%
(also in combination with graphite, bronze, and glass)

up to 30%
  • increased comprehensive strength
  • increased hardness
  • increased wear resistance
  • improved thermal conductivity
  • good dry running properties
  • electrically conductive at higher filler contents
  • resistant to hydrofluoric acid
Graphite
Powder
up to 25%
(also in combination with glass, bronze, and carbon)
  • improved sliding properties
  • reduced coefficient of friction
  • improved thermal conductivity
Bronze
Powder
up to 60%
(also in combination with carbon, graphite, and MoS2))
  • increased comprehensive strength
  • increased hardness
  • increased wear resistance
  • improved thermal conductivity
  • reduced cold flow
Molybdenum disulphide (MoS2)
Powder
up to 5%
(also in combination with glass and bronze)
  • improved sliding properties
  • increased wear resistance
Stainless Steel
Powder
up to 60%
  • improved thermal conductivity
  • reduced cold flow
  • resistant to most chemicals
Pigments
Powder
up to 2%
  • for coloring
    (identification)

 

     
 


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